Championship strugglers Stoke City came from behind to draw 2-2 at Rotherham United courtesy of Bojan Krkic's first goal of the season.
Jurgen Klopp has denied having a row with Xherdan Shaqiri, but the Swiss star says he was surprised to be substituted against Southampton.
Chelsea ended Liverpool's unbeaten start to the season while Tottenham squeezed past Watford and West Ham romped to victory in the EFL Cup.
Leeds United and Middlesbrough both missed out on Championship victories while there were costly defeats for Aston Villa and Stoke City.
It was plain sailing for Leeds United against Preston North End, but West Brom's 4-2 win over Bristol City saw the most compelling action.
Championship leaders Leeds United maintained their unbeaten start in dramatic style, while Derby County boss Frank Lampard was sent off.
Gareth Southgate has told Jack Butland his place in the England squad is not under threat despite playing second-tier football.
Derby County and West Brom recorded vital wins in the Championship as Aston Villa and Stoke City slumped to concerning defeats.
Eric Maxim Choupo-Moting has left Championship side Stoke City for Ligue 1 giants Paris Saint-Germain in a deadline day switch.
Cameroon international Eric Maxim Choupo-Moting and Bayern Munich left-back Juan Bernat are set to join PSG, Thomas Tuchel has confirmed.